2-Azido-1-(4-methylphenyl)ethanone

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2-Azido-1-(4-methyl­phen­yl)ethanone

In the mol-ecule of the title compound, C(9)H(9)N(3)O, the angle formed by the least-squares line through the azide group with the normal to the plane of the benzene plane ring is 46.62 (16)°. The crystal structure features C-H⋯O hydrogen bonds, which link the mol-ecules into zigzag chains running parallel to [010].

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2-Azido-1-(4-nitro­phen­yl)ethanone

In the title compound, C(8)H(6)N(4)O(3), the ketone [C-C(=O)-C] and nitro groups are tilted with respect to the benzene ring by 18.92 (6) and 24.11 (15)°, respectively. In the crystal, mol-ecules are linked into inter-woven chains running parallel to the [100] direction by C-H⋯N hydrogen bonds and weak π-π stacking inter-actions, with centroid-centroid separations of 3.897 (3) Å.

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2-Azido-1-(4-fluoro­phen­yl)ethanone

The crystal structure of the title compound, C(8)H(6)FN(3)O, is stabilized by C-H⋯O hydrogen bonds, which link the mol-ecules into chains running parallel to the a axis.

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4-Azido-2-chloro-6-methyl­quinoline

In the title compound, C(10)H(7)ClN(4), the quinoline ring system is planar [maximum deviation 0.0035 (10) Å]. The crystal structure is stabilized by van der Waals and π-π stacking inter-actions [centroid-centroid distance 3.6456 (17) Å].

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Potassium [(1S)-1-azido-2-phenyl­eth­yl]trifluorido­borate

The title compound, K(+)·C(8)H(8)BF(3)N(3) (-), is a salt containing the chiral organic trifluorido-borate anion. The organic anions and potassium cations are tightly bound to each other by the coordination K-F [2.654 (3)-3.102 (3) Å] and K-N [2.951 (4)-3.338 (4) Å] inter-actions. Thus, the potassium cation adopts a nine-vertex coordination polyhedron, which can be described as a distorted mono...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812018491